Resumen de Inorganic Electrosynthesis: a Green Chemical Method for tin Complexes
Víctor Manuel Jiménez Pérez, Blanca M. Muñoz Flores, B. I. Kharisov, Eugenio Hernández Fernández, Susana Alonso López, Noemí Aksman, Rosalba Ramírez Durón
SnIV complexes of the series of bulky amines have been reported by electrochemical oxidation (3 h) of a tin anode in a cell containing methanol solution of the corresponding bulky amine. All were full characterized by 1H and 13C-NMR, IR, and high resolution mass spectrometry. However, all were not enough soluble in organic solvent in order to record its 119Sn-NMR spectra, this unusual behavior was attributed to the polymeric association thought intermolecular coordination OSn.
