Inorganic Electrosynthesis: a Green Chemical Method for tin Complexes

• Jiménez Pérez , Víctor Manuel ^[1] ; Muñoz Flores , Blanca M. ^[1] ; I. Kharisov, Boris ^[1] ; Hernández Fernández , Eugenio ^[1] ; López Cortina, Susana ^[1] ; Aksman, Noemí ^[1] ; Ramírez Durón , Rosalba ^[1]
  1. [1] Universidad Autónoma de Nuevo León

     Universidad Autónoma de Nuevo León

     México

     
• Localización: Química Hoy, ISSN-e 2007-1183, Vol. 1, Núm 3, 2011 (Ejemplar dedicado a: Abril-Junio 2011), págs. 28-31
• Idioma: inglés
• Enlaces
  • Texto completo
• Resumen

  • SnIV complexes of the series of bulky amines have been reported by electrochemical oxidation (3 h) of a tin anode in a cell containing methanol solution of the corresponding bulky amine. All were full characterized by 1H and 13C-NMR, IR, and high resolution mass spectrometry. However, all were not enough soluble in organic solvent in order to record its 119Sn-NMR spectra, this unusual behavior was attributed to the polymeric association thought intermolecular coordination OSn.