Resumen de Bioreceptivity optimisation of concrete substratum to stimulate biological colonisation
Sandra Manso Blanco
The lack of green areas in cities is caused by the increase in population and the urbanisation process. However, an increasing interest in city greenery was observed since the beginning of twentieth century. Several benefits are associated with green areas from a social, economic and ecologic point of view. Consequently, the solution to increase the urban green spaces lies in their inclusion on structures¿ surfaces. In that sense, a number of different technologies were developed which can be grouped into green walls and green roofs. Unfortunately, existing systems for both green walls and green roofs present several disadvantages in terms of installation and maintenance costs, low level of integration with the structure, extra loads, limitations in their use in rehabilitation projects, and others. The general objective of this dissertation is to provide a first approach to the possibility of using a structure surface as biological substratum. This was treated considering two different research lines. The first research line includes the modification of the chemical and physical properties of the cementitious material, which will be used as substratum. Then, the second issue is the evaluation of materials¿ bioreceptivity under both laboratory and environmental conditions. Regarding the material, chemical properties were firstly studied. pH was taken as a priority from the diversity of involved chemical properties. In that sense, two different ways to obtain a low pH cementitious material were studied. First, it was attempted to reduce the pH of the most common hydraulic binder, Ordinary Portland Cement (OPC). Then, the characterisation of Magnesium Phosphate Cement (MPC) as a hydraulic binder of naturally low pH was carried out. Insufficient reduction in the pH of OPC was obtained and properties such as flexural and compressive strength were highly affected. In contrast, positive results were obtained regarding the use of MPC as hydraulic binder for the specific purpose to be used as a biological substratum. Regarding the physical properties, porosity and roughness were the main properties considered. For that purpose, modifications were made to the composition of different samples, by means of modifying the hydraulic binder, granular skeleton, the water to cement ratio and the amount of cement paste. The methodology used for the estimation of the optimal cement paste content worked well for OPC specimens although MPC responded differently. The characterisation of the twenty-three initial materials¿ bioreceptivities provided significantly different results. Consequently, six different mix designs were selected to be exposed to colonisation.
