This thesis develops and validates a comprehensive experimental methodology for detecting and characterizing depth-dependent vector magnetization states in nanoscale multilayers, addressing a longstanding challenge in magnetism and spintronics where non-collinear spin structures are central yet rarely measured directly. The work establishes a solid methodological base by experimentally verifying the linear magneto-optical reflection matrix and demonstrating a linear superposition approach for multilayer magneto-optical signals. Building on this, the generalized magneto-optical ellipsometry method enabled the unambiguous identification of non-collinear magnetization profiles and the achievement of full, layer-resolved vector magnetometry for multilayers with two ferromagnetic thin films, revealing field-dependent magnetization rotations and uncovering anomalous out-of-plane signals attributable to interlayer Dzyaloshinskii Moriya interactions. These advances were made possible through the careful design and fabrication of high-quality multilayers and supported by macrospin simulations that reproduced the observed behaviors. Altogether, the thesis provides a robust framework for layer-resolved vector magnetometry and contributes new insights into the complex physics governing magnetic multilayers.
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