Poly(diphenylacetylene)s: Design, Synthesis and Application

• Autores: Juan José Tarrío Cordeiro
• Directores de la Tesis: Emilio Quiñoá Cabana (dir. tes.), Félix Manuel Freire Iribarne (dir. tes.)
• Lectura: En la Universidade de Santiago de Compostela ( España ) en 2022
• Idioma: inglés
• Tribunal Calificador de la Tesis: Carlos Jiménez González (presid.), Delia Miguel Álvarez (secret.), María Ribagorda Lobera (voc.)
• Programa de doctorado: Programa de Doctorado en Ciencia y Tecnología Química por la Universidad de Santiago de Compostela y la Universidad de Vigo
• Materias:
  • Química
    • Química macromolecular
      • Análisis de polímeros
      • Síntesis de macromoléculas
    • Química orgánica
      • Estereoquímica y análisis conformacional
• Enlaces
  • Tesis en acceso abierto en: MINERVA
• Resumen

  • This Doctoral Thesis is focused on the development of new chiral materials based on poly(diphenylacetylene)s (PDPA). PDPAs are a family of helical polymers generally described as very stable and static, where the secondary structure —helical sense and/or elongation— cannot be modulated by external stimuli. Therefore, in this work we have explored different approaches to synthesize the first reported dynamic PDPAs, which has allowed us to create new stimuli-responsive materials. In addition, we have also focused on the elucidation of the secondary structure of those polymers to understand their structure-function relationship. These results can help the future rational design of novel smart materials with specific properties.