This Ph.D. was carried out in the frame of the cotutelle International Doctoral Programdeveloped between the University of Bordeaux and the University of the Basque Country.The experimental works were performed at Institut de Chimie de la Matiere Condenseede Bordeaux and Centro de Fsica de Materiales. The project was funded by Initiatived'excellence de l'universite de Bordeaux IdEx - Programme investissements d'avenir.
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