Metal complexes of polytopic hydrazone ligands: synthesis, characterization and properties

• Autores: Sabina Rodríguez Hermida
• Directores de la Tesis: Ana Belén Lago Blanco (codir. tes.), Ezequiel M. Vázquez López (codir. tes.)
• Lectura: En la Universidade de Vigo ( España ) en 2013
• Idioma: inglés
• Tribunal Calificador de la Tesis: Roberto Cortés Montero (presid.), Rosa Carballo Rial (secret.), Nora Kulak (voc.)
• Materias:
  • Física
    • Física del estado sólido
      • Cristalografía
  • Química
    • Química inorgánica
      • Compuestos de coordinación
  • Ciencias tecnológicas
    • Tecnología de materiales
      • Propiedades de materiales
• Enlaces
  • Tesis en acceso abierto en: Investigo
• Resumen

  • Six organic ligands based on bis-aroylhydrazone skeleton have been designed and synthesized. Their coordinative behaviour towards different metallic centres such as Cu(I), Cu(II), Co(II), Ni(II) and Zn(II) has been investigated. Special effort is done to obtain single-crystals in order to determine the crystal structure of the compounds and their supramolecular association and arrangement at the solid state. The properties of the compounds obtained depending on their intrinsic characteristics have been also investigated, such as, for example, luminescence and dynamism.