Computational modelling of organometallic reactivity: the model matters

Agustí Lledós

The synthesis, symmetry and applications of interlocked molecules

Stephen M. Goldup

Molecular editing of aromatic heterocycles with organometallic reagents

Mark R. Crimmin, Siim Kaukver, Matei Situra

Shaping three-membered carbocycles via diazo compounds and metal-carbene intermediates

Javier Carreras Pérez-Aradros

Ligand π-extension as a design principle in photoactive cyclometalated iridium chemistry

Gema Durá Gracia

Supramolecular control of luminescence in Au(I) and Pt(II) complexes

Laura Rodriguez

Reaction mechanisms for the transformation of CO2 and CH4

Ainara Nova Flores

Illuminating organometallics: examples of light controlled photophysics, sensing, or circularly polarized emission

Zoraida Freixa Fernández

Unsaturated chiral-at-metal Rhodium(III) complexes bearing achiral SiN-type ligands

María Vega, Itxaso Bustos Rosas, Unai Prieto Pascual, Zoraida Freixa Fernández, Miguel Ángel Huertos Mansilla

Boosting Co-catalytic activity in cyclotrimerization reactions with cationic phosphine ligands

Andrea Olmos Vergé, Diana Martínez Gutiérrez, Carmen Ramírez de Arellano Sánchez, María Cárcel

Ferrocene–gold bimetallic complexes as redox-active anticancer agents

Marta Redrado, Juan Carlos Pérez Sánchez, Gilles Gasser, Mª Concepción Gimeno Floría

Internal light-activated cyclometalated Ir(III) photosensitizers for PDT

Vanesa Fernández Moreira, Eva Morales Pioz, Marta Redrado, Pierre Mesdom, Manuela Pedrón Nicolau, Giulia Salluce, Gilles Gasser

Towards the industrialization-amenable continuous production of enantiopure substances through the rational design of immobilized chiral organometallic catalysts for continuous-flow processes

Montserrat Diéguez Fernández

Sodium mediated C–H (multi)silylation of (hetero)arenes

David Sanchez Roa, Eva Hevia

Copper(I) complexes for user friendly and efficient catalytic applications

Silvia Díez González

Scorpionate-derived Al-Mg heterobimetallics as boosted catalysts for the cooperativering-opening polymerization of lactides

Luis Fernando Sánchez Barba, David González Lizana, Marta Navarro, Andrés Garcés, Agustín Lara Sánchez

Calcium-driven catalysis for CO2 activation, fixation, and hydroboration reduction

Marc Martínez de Sarasa Buchaca, Enrique Francés Poveda, Antonio Rodríguez Diéguez, Pablo Salcedo Abraira, José Antonio Castro Osma, Felipe de la Cruz Martínez, Agustín Lara Sánchez

Open-shell Ir(II): a platform for unlocking new catalysis

Macarena G. Alférez, Jesus Campos Manzano

C–H activation as a strategy for C–N bond formation from hydrocarbons and dinitrogen

Nereida Hidalgo Reinoso

Dehydrogenative coupling reactions catalysed by NHC-iminophosphorano iridium complexes

Sergio García García, Jesús J. Pérez-Torrente, Vincenzo Passarelli

Naphthalene diimide-based Ru(II) complexes for photodynamic therapy: impact of ligand functionalization on photophysical and biological properties

María Sánchez Migallón, Carlos Eduardo Navarro Restrepo, Anna Massaguer Vall-Llovera, Blanca Rosa Manzano Manrique, Gema Durá Gracia

Red-light-activated Ru(II) intracellular photocatalysis perturbs cancer redox homeostasis

Mikel Gabino García, María Gil Moles, Mª Concepción Gimeno Floría

Cyclometallated Pt(II) co-crystals: photophysical properties and theoretical understanding

Mar Inés García, Sergi Burguera Piña, Antonio Frontera Beccaria, Andrea Pinto, Laura Rodriguez

Visible-light-assisted dehydrogenation of benzylamines catalysed by a standalone ruthenium complex

Laura Ibáñez Ibáñez, Mario del Pico Carranza, Gregorio Guisado Barrios, Jose A. Mata

Gem-selective N-Alkenylation of Uracil derivatives via Rh(I)‒NHC catalysis

Mert Olgun Karataş, Belinda Español Sanchez, Cristian Viezure, Ricardo Castarlenas Chela

A triplet aura-nitrene

Jaime Martín, Marc Fernández Sabaté, Bernhard Spingler, John H. Beale, Dominik Munz, Cristina Nevado

Gold-thiopurine and thioguanine platforms for chemotherapy and photodynamic therapy

Laura Agulló Antón, Juan Carlos Pérez Sánchez, María Gil Moles, Mª Concepción Gimeno Floría

Photoswitchable chiral-at-metal Iridium(III)-DTE complexes

Iraitz Aldasoro, Jokin Saizar, Pablo R. G. Valle, Ariadna Pazos Pérez, Zoraida Freixa Fernández

Highly efficient visible-light photocatalytic oxidation of sulfides to sulfoxides using cyclometalated Pt(II) complexes

Lucía Barreras Calleja, Elena Lalinde Peña, María Teresa Moreno García, Julio Jacinto Fernández Cestau

Enhancement of TiO2 photocatalytic activity by Cu(I) complexes: In-situ synthesis and application in Rhodamine 6G degradation

Jesús R. Berenguer Marín, Marta Martín Casado, Janira Herce, Miguel Angel Rodríguez Barranco, Elena Serrano Torregrosa, Javier García Martínez

Ni-catalyzed Suzuki-Miyaura couplings of poly-fluorinated arenes and boronic acids

Gabriela Bulnes Vides, María Trinidad Martín García, María Auxiliadora Prieto Cárdenas, María del Carmen Nicasio Jaramillo

Cationic zinc alkoxides in ε-caprolactone ring opening polymerization

Juan Cámpora Pérez, María del Pilar Palma Ramírez, Juan Manuel Delgado Collado, Francisco J. Fernández de Cordova, Antonio Rodríguez Delgado

Expanding the catalyst scope for the asymmetric hydrogenation of tetrasubstituted olefins: a machine learning approach

Enric Castillo i Hidalgo, Maria Biosca, María Besora Moreno, Joan Ferré Baldrich, Eduardo Aguilar Bejarano, Simon Woodward, Oscar Pàmies, Montserrat Diéguez Fernández

Cyclometalated and alkynyl ligand effects in iridium (III) complexes: synthesis, isomerism, and photophysical properties

Andrea Corral Zorzano, Mónica Martínez Junquera, Elena Lalinde Peña, María Teresa Moreno García

Reactivity of terminal alkynes at the coordination sphere of an osmium polyhydride complex

Sheila Galván Curto, Joaquín M. Granados, Enrique Oñate, Montserrat Olíván Esco

Expanding the coordination chemistry of organosilver (III): a unique six-coordinate 20-VE complex

Alba de Toro Molina, Luca Demonti, Daniel Joven Sancho, Antonio Martin, Nathalie Saffon Merceron, Miguel Baya García, Noel Nebra Muñiz

Mesoionic carbene-based (OCCO) ligands for molybdenum and manganese: towar drobust platforms for dinitrogen activation

Mario del Pico Carranza, Marta Martín Casado, Gregorio Guisado Barrios

Exploring gallium(III) complexes as emerging therapeutic candidates for breast cancer

Elena Domínguez Jurado, Alberto Moreno Fernández, Marc Martínez de Sarasa Buchaca, Sofía Blas, María del Mar Noblejas López, Carmen Moya, Fernando de Andrés Segura, Iván Bravo, José Daniel Aroca Aguilar, Jesús José Ferre Fernández, Julio Escribano, Antonio Rodríguez Diéguez, Pablo Salcedo Abraira, Santiago García-Yuste, Carlos Alonso Moreno, Agustín Lara Sánchez

Profiting from light-induced metal-to-metal intramolecular electron transfer: towards highly efficient heterodinuclear photosensitizers for photodynamic therapy

Juan Sanz Villafruela, Lisa Marie Servos, Nicolás Montesdeoca, José Vicente Cuevas Vicario, Artur J. Moro, João Lima, Marta Martínez Alonso, Gustavo Espino Ordóñez, Johannes Karges

Shielded yet reactive: rind germylenes in transition metal coordination

Lukas Fischer, Jesus Campos Manzano

One-pot synthesis of enantiopure alcohols combining Organolithium Reagents (RLi) and Alcohol Dehydrogenases (ADHs) under bench-type conditions

Gloria Moris Menéndez, Nicolas Rios Lombardia, Iván Lavandera García, Vicente Gotor Fernández, Joaquin Garcia Alvarez

From molecular design to surface sensors: gold–naphthalimide complexes with silatranephosphine anchors

Pablo R. G. Valle, Ariadna Pazos Pérez, Juan José Gómez Cadenas, Mª Concepción Gimeno Floría, Zoraida Freixa Fernández

2-[(dimethylamino)methyl]phenyl-stabilized heavier tetrylenes: syntheses, coordination chemistry and air- and moisture-stability

Sergio García Vega, Sergio Aguado Rivero, Javier A. Cabeza, Pablo García Álvarez, Mar Gómez Gallego, Miguel Ángel Sierra Rodríguez

Metal influence on emission characteristics in d⁸ Pt(II) and Au(III) complexes: modulation by strong-field auxiliary ligands

Iker Gil Gómez de Segura, Oussama El Barnoussy, Antonio Martin, Manfred Bochmann, Elena Lalinde Peña, Julio Jacinto Fernández Cestau

Synthesis and characterization of new gold (I) carbenoid complexes

René Iván González Fernández, Manuel Romero Fructos-Vázquez, Pedro José Pérez Romero

Half-sandwich Ir(III) complexes with π-extended N^N ligand for efficient PDT

Caros Gonzalo Navarro, Juan Ángel Organero Gallego, Lucía Santos, Ana M. Rodríguez, Anna Massaguer Vall-Llovera, Blanca Rosa Manzano Manrique, Gema Durá Gracia

Ring-opening polymerization of bio-based macrolactones catalyzed by sodium aryloxide complexes with multi-functional alcohol initiators

Rocío Hernández García, Valentina Sessini, Marta Elena González Mosquera

Mild and selective dichlorination reactions using Co and cationic ligands complexes

Jorge Herrera, Jordi Pastor Garcia, Carmen Ramírez de Arellano Sánchez, Andrea Olmos Vergé

A nanosized metallobox for the encapsulation of pincer complexes

Susana Ibáñez Maella, Sebastián Martínez Vivas, Macarena Poyatos de Lorenzo, Eduardo Víctor Peris Fajarnés

Efficient, selective and environmentally friendly titanium-based catalysts for the epoxidation of bio-derived substrates using H2O2 as primary oxidant

Gerardo Javier Jiménez Pindado, Javier Jiménez, Diego Martínez, María Vanessa Tabernero Magro

Calcium catalysts for the synthesis of cluster-triggered emission biopolymers

Agustín Lara Sánchez, Felipe de la Cruz Martínez, Enrique Francés Poveda, Jesús Naranjo, Cristina Martín Álvarez, Karina Duenas, Òscar Gulías Borau, Santi Nonell Marrugat, Roger Bresolí Obach

Germylenes in the spotlight, long lived photoexcited germylenes properties and reactivity

Félix León García, Enrique Soto, Jesus Campos Manzano

Synthesis of secondary thioamides via chloride-catalyzed reaction of nitrones and carbon disulfide

Marcos López Aguilar, Nicolas Rios Lombardia, Daniel Barrena Espes, Miguel Gallegos González, Joaquin Garcia Alvarez, Carmen Concellón Fernández, Vicente del Amo Sánchez

Effect of hexafluoroisopropanol (HFIP) in the copper-catalyzed C–H functionalization of alkanes via carbene insertion

Manuela Márquez Domínguez, Manuel Romero Fructos-Vázquez, María Mar Díaz Requejo, Pedro José Pérez Romero

Photoinduced electron transfer enhances the tumor-targeted photodynamic activity of bombesin metallopeptides incorporating an Ir(III) complexand carboxyfluorescein

Elisenda Zafon, Gerard Riesco Llach, Igor Echevarría Poza, Marta Martínez Alonso, Marta Planas, Lidia Feliu Soley, Gustavo Espino Ordóñez, Anna Massaguer Vall-Llovera

Electrocatalytic routes for long-term sustainable hydrogen storage

Christian Bachmann, Carmen Mejuto Nieblas, Elena Mas Marzá, Iván Sorribes Terrés, Francisco Fabregat Santiago, Jose A. Mata

Orthopalladation of N substituted (Z) 4-Arylidene-5(4H)-Oxazolones: synthesis,photophysical properties and density functional theory studies of the C-H bond activation

Jesús Moradell, Juan Vicente Alegre Requena, Esteban P. Urriolabeitia

Chemoselective concurrent Meyer-Schuster/C-P bond formation controlled by Brønsted Acidic Deep Eutectic solvents: synthesis of allyl phosphine oxides

Gloria Moris Menéndez, Nicolas Rios Lombardia, Marina María Ramos Martín, Alejandro Presa Soto, Joaquin Garcia Alvarez

Nitrate activation at copper through ligand based redox chemistry

David Nuño, Sara Malagón, Marta Martín Casado, José A. López, Inés García Rubio, María Cristina Tejel Altarriba, Ana Maria Geer Ramos

Chiral 2-Aryl-2-aminoethanols via a photoredox/metal-catalyzed C(sp3)–C(sp2) coupling

Paula Oroz Mateo, Carmen Bretón Beltrán, Eduardo Tomé, Francisco Corzana López, Jesús Héctor Busto Sancirián, María del Mar Zurbano Asensio, Alberto Avenoza Aznar, Jesús Manuel Peregrina García

Room temperature phosphorescence through charge transfer in asymmetric gold(i) phosphine complexes

Andrea Pinto, Llorenç Salazar, Laura Rodriguez

CF3 enabled stabilization of Pd(IV) in organopalladium chemistry

Juan Pueyo, Daniel Joven Sancho, Antonio Martin, Miguel Baya García, Babil Menjón

Computationally guided synthesis of unsupported Au(I)-Pt(II) complexes

Félix Reboiro Sáez, Oliver Baltar Ruiz-Olalla, Daniel Blasco Santana, María Elena Olmos Pérez, José María López de Luzuriaga Fernández, Miguel Monge Oroz

First-row transition metal catalysis of unactivated alkenes via Tp and cationic phosphine ligands

Humberto A. Rodríguez, Hugo Domínguez Valenzuela, Jordi Gomis Guardiola, Rubén Piris, Carmen Ramírez de Arellano Sánchez, Andrea Olmos Vergé

Room-Temperature Catalytic Oxidation of 5-Hydroxymethylfurfural (HMF) to 2,5-Furandicarboxylic Acid (FDCA) over Graphene-Supported Iridium nanoparticles

David Ruiz Almoguera, Iván Sorribes Terrés, Jose A. Mata

Shortcut to highly fluorescent perylene derivatives: from fluoranthene fissure-couplingto late-stage aromatic extension

Judith Sala, Lorena Capdevila i Güell, Cristina Berga, Araceli de Aquino, Teodor Parella Coll, Lluís Blancafort San José, Laura Rodríguez, Sílvia Simon, Xavier Ribas Salamaña

Cooperative CO₂ Activation and Catalysis by Pt–Ge Systems

Christian Sánchez Sierra, Joaquín Andrés Lopez Serrano, Jesus Campos Manzano

Upgrading of biomass-sourced molecules with g-C3N4/AuAg catalysts under visible light

Leticia Santamaria Arana, Félix Reboiro Sáez, Olaya Piteiro Fidalgo, Isabel Esteban Díez, José María López de Luzuriaga Fernández, Miguel Monge Oroz

Reactivity of manganese complexes supported by piperazine-based ligands

J. C. Serrano, José A. López, M. P. García, A. Elduque, Ana Maria Geer Ramos

Synthesis of heterostructures based on plasmonic AuAg nanoparticles grafted on Prussian Blue analogues: photocatalytic and photothermal properties

Inés Soldevilla Garrido, Clara Casado Coterillo, Aurore Larquey, Saad Sene, Joulia Larionova, José María López de Luzuriaga Fernández, María Rodríguez Castillo, Yannick Guari, Miguel Monge Oroz

Sugar-functionalization of Ir(III) complexes: impact on photophysical and biological properties

María Tejera Ruiz, Andrea Benedí Visiedo, Isabel Marzo Rubio, Vanesa Fernández Moreira

Novel radical methodologies for the construction of sulfur and selenium stereogenic centers via photoredox catalysis

Alberto León, Miguel Fontecha Barriuso, Paula Oroz Mateo, Eduardo Sainz, Iván Olagaray Benito, Jesús Héctor Busto Sancirián, Jesús Manuel Peregrina García, Miguel Torres Soto

Synthesis, structure and photophysical properties of oxazolones derived from the kaede protein: amplification of the fluorescence

Esteban P. Urriolabeitia, Cosmina Bohan, Jesús Moradell, Alexandra Pop, Anca Silvestru

The heavier group 13-based compounds in Lewis acid-catalyzed carbon dichalcogenide utilization: examples from polymerization and ring-expansion reactions

Christopher John Whiteoak, Cristina García Nievas, Santiago Gullón Moreno, Diego Jaraba Cabrera, Alex Hamilton, Marta E. G. Mosquera