Studies on the effect of pH on the sorption of Pb2+ and Cd2+ ions from aqueous solutions by Caladium bicolor (Wild Cocoyam) biomass

• Michael Horsfall Jnr ^[1] ; Ayebaemi I. Spiff ^[1]
  1. [1] University of Port Harcourt

     University of Port Harcourt

     Nigeria

     
• Localización: Electronic Journal of Biotechnology, ISSN-e 0717-3458, Vol. 7, Nº. 3, 2004, págs. 14-15
• Idioma: inglés
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• Resumen

  • Environmental protection requires the use of natural products instead of chemicals to minimize pollution. This investigation studies the use of a non-useful plant material as naturally occurring biosorbents for the removal of cationic pollutants in wastewater. The effect of pH on the sorption of Pb2+ and Cd2+ ion onto Caladium bicolor corm biomass was investigated. The experimental results have been analysed in terms of Langmuir, Freundlich and Flory-Huggins isotherms. The data showed that the maximum pH (pHmax) for efficient sorption of Pb2+ was 7.0 and for Cd2+ 5.0. Evaluation using Langmuir equation gave the monolayer sorption capacity as 88.50 mg/g and 65.50 mg/g at the respective pHmax for Pb2+ and Cd2+. Surface characterization of acid and base treated C. bicolor biomass indicates a physiosorption as the predominant mechanism for the sorption process. The thermodynamic assessment of the metal ion - Caladium bicolor biomass system indicates the feasibility and spontaneous nature of the process