A one step functionalization, coordination of n3p3cl6 using [cpfe(dppe)sc6h4oh]+

• C Díaz ^[1] ; E Spodine ^[1] ; Y Moreno ^[2] ; E Carrasco ^[1]
  1. [1] Universidad de Chile

     Universidad de Chile

     Santiago, Chile

     
  2. [2] Universidad de Concepción

     Universidad de Concepción

     Comuna de Concepción, Chile

     
• Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 49, Nº. 3, 2004, págs. 205-207
• Idioma: inglés
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• Resumen

  • The new iron-thiolate complex [CpFe(dppe)SC6H4OH]PF6 (1), prepared by the oxidative addition of CpFe(dppe)I (2) to HSC6H4OH (3), reacts in one step with N3P3Cl6 (4) in acetone to give the hexanuclear iron-triolate complex N3P3[CpFe(dppe)SC6 H4O]6 (5), the first cyclotriphosphazene containing thiolate groups coordinated to a metal. Electrochemical data suggest the absence of electronic communication between the iron centers. Magnetic properties for the new complexes are discussed