The stereoselective synthesis of the werner complex with substoichiometric sugars

• JOSÉ PARADA ^[1] ; GUILLERMO LARRAZÁBAL ^[1] ; PEDRO AGUIRRE ^[1] ; SANTIAGO ZOLEZZI ^[1] ; CARMEN VEGA ^[1] ; CRISTIAN GARRIDO ^[1]
  1. [1] Universidad de Chile

     Universidad de Chile

     Santiago, Chile

     
• Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 53, Nº. 1, 2008, págs. 1379-1381
• Idioma: inglés
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• Resumen

  • A tetranuclear complex of Co(III) with hydroxo bridges, so-called "Werner Complex", was synthesized in the presence of several sugars (1-8) with partial resolution of this complex. The sugars in 10 mol % with respect to Co(III) induce maximum resolution of the Werner complex