2,4,6-trimethylpyridinium chlorochromate (tmpcc) as an efficient and novel oxidizing agent for the chemoselective oxidation of alcohols to the corresponding carbonyl compounds

LOTFI SHIRI ^[1] ; ARASH GHORBANI-CHOGHAMARANI ^[1]
1. [1] Ilam University
  
  Ilam University
  
  Irán
Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 54, Nº. 2, 2009, págs. 191-193
Idioma: inglés
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Resumen
- A simple and efficient chemoselective oxidation of alcohols to the corresponding aldehydes and ketones using 2,4,6-trimethylpyridinium chlorochromate (TMPCC) in acetonitrile was described. A good range of primary and secondary benzylic alcohols was selectively oxidized under reflux conditions in good to excellent yields.