Synthesis, characterization of a new carbonylated zirconium metallocene using a dichloro-zirconocene derived from partially alkylated s-indacene

• J.F ARANEDA ^[1] ; S SALINAS ^[1] ; D MAC-LEOD-CAREY ^[1] ; A MUÑOZ-CASTRO ^[2] ; R ARRATIA-PEREZ ^[1] ; C ADAMS ^[1] ; I CHÁVEZ ^[1] ; J.M MANRÍQUEZ ^[1]
  1. [1] Pontificia Universidad Católica de Chile

     Pontificia Universidad Católica de Chile

     Santiago, Chile

     
  2. [2] Universidad Andrés Bello

     Universidad Andrés Bello

     Santiago, Chile

     
• Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 54, Nº. 3, 2009, págs. 269-273
• Idioma: inglés
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• Resumen

  • This work describes the synthesis and characterization of new organometallic species, an unprecedented mononuclear zirconium complex bearing a tetraalkylated s-indacene ligand, and secondly, its respective dicarbonyl complex obtained by reduction with Mg/HgCl2. Theoretical calculations of these two compounds were carried out to gain further understanding of these novel molecular systems.