Poly(sodium-10-undecylenate) as pseudo-stationary phase in the separation and quantification of polyaromatic hydrocarbons by micellar electrokinetic chromatography

• EDUARDO D PEREIRA ^[1] ; BERNABÉ L RIVAS ^[1] ; IVÁN PERIC ^[1] ; PAOLA GALLEGOS ^[1] ; VALESKA FIGUEROA ^[1]
  1. [1] Universidad de Concepción

     Universidad de Concepción

     Comuna de Concepción, Chile

     
• Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 55, Nº. 1, 2010, págs. 31-34
• Idioma: inglés
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• Resumen

  • In this work we reported the synthesis of different molar mass fraction of poly(sodium-10-undecylenate) (PSU), and its subsequent utilization as pseudostationary phase in the separation of a mix of 4 polyaromatic hydrocarbons (PAHs); naphthalene (NAPH), fluorene (FLU), phenantrene (PHEN) and pyrene (PYR). Concentration and molar mass fraction of PSU were the main variable studied. The analytical parameters; efficiency (N), selectivity (a), and resolution (R) were calculated to assess the separation capacity. The best conditions for the separation were achieved using a buffer composed by 12.5 mM of each sodium borate and sodium hydrogen phosphate, yielding pH 9.2 in ACN/H2O (40/60) solvent, using PSU of molar mass fraction 30-50 kDa in concentration of 0.25 g 100 mL-1. The applied voltage was 25 kV. Finally, Limit of Detection (LOD) and Limit of Quantification (LOQ) for 4 PAHs were calculated from the calibration curves in optimal separation conditions.