Synthesis of unsaturated esters via highly efficient esterification catalyzed by polymer grafted quarternary ammonium salts as triphase catalysts

• ZHENG YONG LIANG ^[1] ; LILI WANG ^[2] ; HUI LIU ^[1] ; JIN SHUO HUANG ^[1]
  1. [1] Zhengzhou University

     Zhengzhou University

     China

     
  2. [2] Henan University of Traditional Chinese Medicine

     Henan University of Traditional Chinese Medicine

     China

     
• Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 58, Nº. 1, 2013, págs. 1558-1561
• Idioma: inglés
• Enlaces
  • Texto completo
• Resumen

  • A series of unsaturated esters were prepared via condensation of sodium carboxylates and alkenyl halide under the condition of macroporous polystyrene grafted quarternary ammonium salt as recyclable phase transfer catalyst, NaI as co-catalyst, Cu powder as inhibitor and H2O as solvent. Under optimal conditions, products yields are 78.2~ 96.0%. The catalyst can be convenient recycled and reutilized for about five times without losing its activity obviously.