Preparation of anion-exchange cellulose for the removal of chromate
- Autores: Özgür Arar
- Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 64, Nº. 2, 2019, págs. 4471-4474
- Idioma: inglés
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Resumen
The quaternary ammonium group containing cellulose was prepared by the one-pot method and applied for the removal of chromate (CrO42−) ions from aqueous solution. The prepared sorbent was characterized by using elemental analyzer and Fourier transform infrared (FTIR) spectroscopy. Its ion exchange behavior toward CrO42− ions was investigated as a function of sorbent dose and initial solution pH. The kinetic and sorption equilibrium experiments were also carried out in a batch system. Equilibrium data were best fitted with the Langmuir model and the maximum ion exchange capacity of the sorbent was found as 3.8 mg of CrO42−/g sorbent. Moreover, the removal of CrO42− is achieved within 5 minutes. Furthermore, the calculated thermodynamic parameters disclosed that the ion exchange reaction is feasible, spontaneous and exothermic. In addition, the CrO42− ions can be desorbed from the sorbent by 1.0 M HCl solution with 95% regeneration efficiency.
