Effect of temperature and content of chlorurated salt of CU(II), MN(II) or AL(IIII) on the density of acidified seawater and water mixes samples

• Autores: Juan Segovia, Juan M Sandoval, Venecia Herrera Apablaza
• Localización: Journal of the Chilean Chemical Society (Boletín de la Sociedad Chilena de Química), ISSN-e 0717-6309, ISSN 0366-1644, Vol. 67, Nº. 1, 2022, págs. 5462-5467
• Idioma: inglés
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• Resumen

  • The relationship between the density of seawater and acidified mixtures samples in the presence of up to a maximum concentrations of 0.18 m for Cu(II), 0.34 m for Mn(II) or 0.6 m for Al(III), in selected temperatures used in the copper leaching process (283.15 - 313.15 K), showed a positive linear behavior with salinity and cation concentration. The influence of temperature on the density rate changes was similar when comparing the three solutes in acidified solutions of different salinity. The effect of temperature on the change in density did not exceed 1% and by concentration, the greatest influence was due to Al(III) with 5.43%, in agreement with its greater relative quantity. The data obtained, using a vibrating tube density meter, were used to analyze and correlate to the Apelblat equation that was favorably applied to calculate the isobaric expansibility coefficient. The temperature had an influence on the isobaric expansibility coefficient values, suggesting a making interaction effect due to majority anions present in the seawater and mixture samples (Cl– > SO4-2), and a breaking interaction effect when the cations Cu(II), Mn(II) or Al(III) were added.