"One pot" Microwave Assisted Synthesis of 5,10,15-Tri(4-Methoxyphenyl)- 20-( 4-Chlorophentyl)-21H,23H-Porphyrin and its Zinc (II) Complex.

• Loredo Calderón, Erika ^[1] ; Martínez Lejía , Carolina ^[1] ; López Cortina, Susana ^[1] ; Muñoz Flores, Blanca ^[1] ; Hernández Fernández , Eugenio ^[1] ; Jiménez Pérez , Víctor ; Cuevas Yañez , Erick ^[2]
  1. [1] Universidad Autónoma de Nuevo León

     Universidad Autónoma de Nuevo León

     México

     
  2. [2] Universidad Nacional Autónoma de México

     Universidad Nacional Autónoma de México

     México

     
• Localización: Química Hoy, ISSN-e 2007-1183, Vol. 2, Núm 2, 2012 (Ejemplar dedicado a: Enero-Marzo 2012), págs. 6-9
• Idioma: inglés
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• Resumen

  • Toe synthesis of new unsymmetrical A,B porphyrin, 5,10,15-tri(4-methoxyphenyl)-20-(4-chlorophenyl)-21H, 23H-porphyrin, 1, and its Zinc(II) complex, 5, 1 O, 15-tri( 4-methoxyphenyl)-20-( 4-chlorophenyl)-21, 23- Zinc(II)-porphine, l, was accomplished using both conventional and "one pot" solventless microwave assisted methods with interesting comparative results. The obtained molecules were characterized by 'H NMR, UV-Vis and MS. These molecules are considered to represent new compounds with potential application as photosensitizers in photodynamic therapy.