Macroporous silicon microreactor for the preferential oxidation of CO
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N.J. Divins [2] ; E. López [2] ; J. Llorca [2] ; D. Vega [2] ; A. Rodríguez [2] ; F. González de Rivera [1] ; I. Angurell [1] ; M. Seco. O. Rossell [1]
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[1] Universitat de Barcelona
Universitat de Barcelona
Barcelona, España
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[2] Technical University of Catalonia-Barcelona tech,
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- Localización: Proceedings of the 2013 Spanish Conference on Electron Devices / Héctor García (aut.), Helena Castán Lanaspa (aut.), 2013, ISBN 9781467346665
- Idioma: español
- Texto completo no disponible (Saber más ...)
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Resumen
A macroporous silicon micromonolith containing ca. 40,000 regular channels of 3.3 μm in diameter per square millimeter has been successfully functionalized with an Au/TiO 2 catalyst for CO preferential oxidation (CO-PrOx) in the presence of hydrogen. The functionalization of the silicon microchannels has been accomplished by growing a SiO 2 layer on the channel walls, followed by exchange with a titanium alkoxyde precursor and decomposition into TiO 2 and, finally, by anchoring carbosilanethiol dendron protected pre-formed Au nanoparticles. Catalytically active centers at the Au-TiO 2 interface have been obtained by thermal activation. With this method, an excellent homogeneity and adherence of the catalytic layer over the microchannels of the macroporous silicon micromonolith has been obtained, which has been tested for CO-PrOx at 363-433 K and λ=2 under H 2 /CO=0-20 (molar). The macroporous silicon micromonolith converts ca. 3 NmL of CO per minute and mL of micro reactor at 433 K under H 2 /CO=20, suggesting that it could be particularly effective for hydrogen purification in low-temperature microfuel cells for portable applications.
