Resumen de Synthesis of novel axially chiral Rh¿NHC complexes derived from BINAM and application in the enantioselective hydrosilylation of methyl ketones
Min Shi, Guo-Bin Rong, Wei-Liang Duan
Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1-binaphthalenyl-2,2-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The corresponding sec-alcohols can be obtained in high yields with good to excellent ee
