Manganese N-confused porphyrin reactivity: CH bond activation and meso carbon reduction

• Autores: Christopher J. Ziegler, John D. Harvey
• Localización: Chemical communications, ISSN 1359-7345, Nº. 23, 2003, págs. 2890-2891
• Idioma: inglés
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• Resumen

  • Manganese N-confused porphyrins activate C¿C and C¿H bonds upon heating or air oxidation; the dimer complex [Mn(NCTPP)]2 is reduced at two meso positions, and the pyridine coordinated monomer breaks the internal C¿H bond upon heating or exposure to oxygen