Excellent enantio-selective enclathration of (2R,3S)-3-methyl-2-pentanol in channel-like cavity of 3-epideoxycholic acid, interpreted by the four-location model for chiral recognition

• Autores: Yasuhito Miyake, Kazuaki Kato, Kazuaki Aburaya
• Localización: Chemical communications, ISSN 1359-7345, Nº. 23, 2003, págs. 2872-2873
• Idioma: inglés
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• Resumen

  • Pure (2R,3S)-3-methyl-2-pentanol is resolved from the racemates by a steroidal host; the interpretation of the recognition mechanism based on the crystal structure reveals that CH/O interaction between the host and guest plays a decisive role in enantio-selective enclathration of the small aliphatic secondary alcohol