A solvothermal synthesis of a novel 1D ladder-like (NH3CH2CH2NH3)AgAsS4 containing N–H⋯S hydrogen bonding

• Autores: Yonglin An, Cuiying Jia, Min Ji, Xuefeng Li, Xin Liu
• Localización: Inorganic chemistry communications, ISSN 1387-7003, Vol. 6, Nº 8, 2003, págs. 1137-1139
• Idioma: inglés
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• Resumen

  • A one-dimensional compound (NH3CH2CH2NH3)AgAsS4 with ladder-like chains was synthesized solvothermally. This compound crystallizes in the monoclinic system, space group C2/c, with a=13.5805(8) Å, b=6.5331(3) Å, c=22.7711(9) Å, α=90°, β=106.42(3)°, γ=90°, Z=8. The rare type hydrogen bonding of N–H⋯S and electrostatic force hold the anionic chains together.