Aromatic-aromatic interaction between metallacycle and phenyl ring

• Autores: Shubhamoy Chowdhury, Michael G.B. Drew, Dipankar Datta
• Localización: Inorganic chemistry communications, ISSN 1387-7003, Vol. 6, Nº 8, 2003, págs. 1014-1016
• Idioma: inglés
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• Resumen

  • The X-ray crystal structure of [CuL2]ClO4 where L is the 1:1 condensate of benzil-monohydrazone and 2-pyridinecarboxaldehyde, reveals unprecedented π–π interaction between the metallacycles and phenyl rings. The interaction is intramolecular.