Novel reactivity of unconjugated diimines with [PtCl 2 (coe)] 2 (coe= cis-cyclooctene)

• Autores: Eric J. Derrah, Haiwen Zhang, Liliya G. Nikolcheva, Christopher M. Vogels, A. Decken, Stephen A. Westcott
• Localización: Inorganic chemistry communications, ISSN 1387-7003, Vol. 6, Nº 8, 2003, págs. 1086-1090
• Idioma: inglés
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• Resumen

  • The addition of unconjugated diimines [ArC(H)NCH2CH2NC(H)Ar, L1: Ar=3-C6H4Bpin (pin=1,2-O2C2Me4), L2: Ar=4-C6H4Bpin, and L3: Ar=4-C6H4OMe] to [PtCl2(coe)]2 (coe=cis-cyclooctene) affords the corresponding dinuclear species [trans-PtCl2(coe)]2L (1–3), where the diimine coordinates in a monodentate fashion to each of the metal centres. Compounds have been characterized by multinuclear NMR spectroscopy, FT-IR spectroscopy, elemental analyses, and for the case of 2, by X-ray diffraction.