Synthesis, structure and properties of a neutral zincophosphate monomer decorated with 2, 2 -bipyridine ligands

• Autores: Zhi-En Lin, Jie Zhang, Shou-Tian Zheng, Guo-Yu Yang
• Localización: Inorganic chemistry communications, ISSN 1387-7003, Vol. 6, Nº 8, 2003, págs. 1035-1038
• Idioma: inglés
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• Resumen

  • A neutral zincophosphate monomer [Zn(2,2′-bipy)]2(H2PO4)4 has been synthesized under hydrothermal condition in the presence of 2,2′-bipyridine ligands. The structure consists of a 4-membered ring formed by vertex-sharing ZnO3N2 square pyramids and H2PO4 tetrahedra, with two H2PO4 groups hanging from the zinc atoms. This compound exhibits intense photoluminescence upon photoexcitation at 388 nm.