The ν6=1 state of fluoroform, HCF3: analysis of the rotational and vibrational spectra

• Autores: G. Graner, G. Duxbury, J. Cosle¿ou, A. Ceausu-Velcescu, J. Demaison, H. Bu¿rger
• Localización: Journal of molecular spectroscopy, ISSN 0022-2852, Vol. 220, Nº 2, 2003, págs. 291-297
• Idioma: inglés
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• Resumen

  • An analysis of the ν6=1 state of fluoroform is performed using rotational and high resolution infrared spectra. Previously radiofrequency data [Chem. Phys. Lett. 214 (1993) 265–270] and millimeter data [J. Mol. Spectrosc. 131 (1988) 1–8] were combined with new millimeter and infrared measurements, and a set of 27 parameters has been derived. A multiple fit analysis was performed confirming the assumption that the ν6=1 excited state is not affected by intervibrational resonances.