Calc-silicate gneisses from the Lower Unit of the Tormes Gneiss Complex, NW Salamanca, exhibit a sequence of reaction textures that have been used to elucidate their retrograde P-T-XCO2 path. The highest temperature recorded in the calc-silicates is represented by the wollastonite- and scapolite- (meionite-rich) bearing assemblages which yield at least 750º C at 6 kbar based on experimental results. The calc-silicates have partially re-equilibrated at lower temperatures (down to 450º C) as evidenced by the successive reactions: (1) Wo + Scp + Cal → Grt + CO2; (2) Wo + CO2 → Cal + Qtz; (3) Scp → Pl + Cal + Qtz; (4) Grt + CO2 + H2O → Ep/Clz + Cal + Qtz ± Pl; y (5) Cpx + CO2 + H2O → Tr + Cal + Qtz. The cooling down to lower temperatures of 450º C (at P <3 kbar), in the andalusite stability field, is also suggested by the secondary andalusite replacement of previous fibrolitic sillimanite in adjacent metapelites. In this paper, mineral devolatilization equilibria are used to constrain the composition of both syn- and post-peak-D2 fluids in the deepest exposed levels of the metamorphic complex. The results indicate that during the transitional granulite facies metamorphism, large-scale CO2 advection did not occur.
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