The Synthesis and Reactions of Nickel(III) Stabilized by a Nitrogen-Donor Macrocycle

• David E. Berry ^[1] ; Suzanne Girard ^[1] ; Alexander McAuley ^[1]
  1. [1] University of Victoria

     University of Victoria

     Canadá

     
• Localización: Journal of chemical education, ISSN 0021-9584, Vol. 73, Nº 6 (June), 1996, págs. 551-554
• Idioma: inglés
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• Resumen

  • This experiment describes the synthesis of 1,4,8,11-tetraazacyclotetradecane and its nickel(II and III) complexes avoiding the use of percholrate anion. The paramagnetic effects in solution and solid state are described for the nickel(III) dihalo derivatives along with a spectrophotometric study.