An Inversion Recovery NMR Kinetics Experiment

• Travis J. Williams ^[1] ; Allan D. Kershaw ^[1] ; Vincent Li ^[1] ; Xinping Wu ^[1]
  1. [1] University of Southern California

     University of Southern California

     Estados Unidos

     
• Localización: Journal of chemical education, ISSN 0021-9584, Vol. 88, Nº 5, 2011, págs. 665-669
• Idioma: inglés
• Texto completo no disponible (Saber más ...)
• Resumen

  • A convenient laboratory experiment is described in which NMR magnetization transfer by inversion recovery is used to measure the kinetics and thermochemistry of amide bond rotation. The experiment utilizes Varian spectrometers with the VNMRJ 2.3 software, but can be easily adapted to any NMR platform. The procedures and sample data sets in this article will enable instructors to use inversion recovery as a laboratory activity in applied NMR classes and provide research students with a convenient template with which to acquire inversion recovery data on research samples.