Synthesis of palm-based ethylhexyl ester as a synthetic base oil for drilling fluids using chemical transesterification

• Autores: N. S. H. A. Habib, R. Yunus, U. Rashid, Y. H. Taufiq-Yap, Z. Z. Abidin
• Localización: Grasas y aceites, ISSN-e 1988-4214, ISSN 0017-3495, Vol. 65, Nº 1, 2014
• Idioma: inglés
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• Resumen

  • In the present study the synthesis of a palm based ethylhexyl ester was examined through a transesterification reaction of palm oil methyl ester (POME) with 2-ethylhexanol (EH). A sodium methoxide in methanol solution was used as a catalyst. The reaction was carried out at a fixed pressure of 1.5 mbar by varying the temperature (80�140 °C), POME/2EH molar ratio (1:1.5�1:2.2), reaction time (0.5�4 h) and catalyst concentration (1�2% w/w). The reaction with 2-ethylhexanol involved a single step reversible reaction, thus, the reaction was completed in a very short time. The optimum conditions were obtained in less than 30 minutes with 1.5 mbar pressure, 70 °C, and 1:2 molar ratio of POME to 2EH. The analysis of the final product (ethylhexyl ester) was performed using gas chromatography which exhibited 98% of ethyl hexyl ester yield. The gas chromatography analysis of ethyl hexyl ester revealed two major esters peaks i.e. ethyl hexyl palmitate and ethylhexyl oleate.