Influence of the electronic effects of phosphine ligands upon the properties of cyclopalladated complexes containing a σ(Pd—Csp2, ferrocene)bond X-Ray crystal structures of [Pd{(η5-C5H5)Fe[(η5-C5H3)C(Me)ξN(C6H4-4-Me)]}Cl(PPh3)] and [Pd{(η5-C5H5)Fe[(η5-C5H3)CH2NMe2]}Cl(PPh3)]