A novel heterometallic m4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcohol

• Autores: Elena A. Vinogradova, Vladimir N. Kokozay, Olga Yu Vassilyeva, Brian W. Skelton
• Localización: Inorganic chemistry communications, ISSN 1387-7003, Vol. 6, Nº 1, 2003, págs. 82-85
• Idioma: inglés
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• Resumen

  • The reaction of copper powder in dmso with cadmium acetate hydrate and 2-dimethylaminoethanol (HL), in open air, afforded [Cd2Cu4(μ4-O)(O2CMe)6L4]·2H2O with a metal skeleton that approximates an octahedron. The copper atoms are tetrahedrally arranged about the oxygen atom in a considerably distorted fashion. The amino alkoxo and acetate ligands display a variety of bonding modes in the complex.