Rigidochromism in metal-centered emission of Rh(III) complexes

• Autores: Leslie S. Forster, John V. Rund
• Localización: Inorganic chemistry communications, ISSN 1387-7003, Vol. 6, Nº 1, 2003, págs. 78-81
• Idioma: inglés
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• Resumen

  • A thermally induced redshift in a metal-centered 3T1->1A1 emission is due to population of the higher energy component of 3T1 , split by a low symmetry field. The population of this level is increased by solvent motion and the redshift then appears as rigidochromism.