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Resumen de Crystal structure and hirshfeld surface analysis of (e)-5-phenyl-3-((4-(trifluoromethyl)benzylidene)amino)thiazolidin-2-iminium bromide

Abel M. Maharramov, Gulnara SH. Duruskari, Gunay Z. Mammadova, Ali N. Khalilov, Javahir M. Aslanova, Jonathan Cisterna, Alejandro Cárdenas, Iván Brito

  • In the cation of the title salt, the central thiazolidine ring adopts an envelope conformation. In the crystal N-H⋯Br hydrogen bonds link the components into a bi-dimensional network with the cations and anions stacked parallel to plane (101). The molecular structure shows several positional disorders over -CF3 and thiazolidine fragments and these were modeled. The weak intermolecular interactions in the crystal structure are mainly constituted by H⋯F, H⋯π and H⋯Br. Hirshfeld surface analysis were used to verify the contributions of the different intermolecular interactions.


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