Addition of Oxime Derivatives to Alkynyl Fischer Carbene Complexes

• González, Héctor F. ^[1] ; Blanco-Lomas, Marina ^[1] ; Rivado-Casas, Laura ^[1] ; Rodrı́guez, Miguel A. ^[1] ; Campos, Pedro J. ^[1] ; Sampedro, Diego ^[1]
  1. [1] Universidad de La Rioja

     Universidad de La Rioja

     Logroño, España

     
• Localización: Organometallics, ISSN 0276-7333, Vol. 31, Nº. 18, 2012, págs. 6572-6581
• Idioma: inglés
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• Resumen

  • The addition of oxime derivatives to alkynyl Fischer carbene complexes has been explored through a combined experimental and computational approach. Up to four different heterocycles with diverse regiochemistry and ring size were found, depending on the starting ketone. The reaction mechanism was studied by DFT methods.