Physical, optical and chemical properties of atmospheric aerosols in the western Mediterranean continental background

• Autores: Anna Ripoll Roca
• Directores de la Tesis: José Andrés Alastuey Urós (dir. tes.), María Rosa Soler Duffour (dir. tes.), María Cruz Minguillón Bengochea (dir. tes.)
• Lectura: En la Universitat de Barcelona ( España ) en 2015
• Idioma: inglés
• Tribunal Calificador de la Tesis: Jeronimo Lorente Castello (presid.), Sergio Rodríguez González (secret.), Nicolas Marchand (voc.)
• Materias:
  • Ciencias de la tierra y del espacio
    • Ciencias de la atmósfera
      • Química atmosférica
    • Meteorología
      • Contaminación atmosférica
• Enlaces
  • Tesis en acceso abierto en:  TDX  Dipòsit Digital de la UB 
• Resumen

  • Atmospheric aerosols have played a key role in the development of the Earth's atmosphere. Without atmospheric particles rainfall would be non existent and the climate would be very different. However, anthropogenic emissions have changed the chemical composition of atmospheric aerosols significantly through emissions of particles and precursor gases, particularly since the industrial revolution. Moreover, numerous studies have demonstrated that atmospheric aerosols, both natural and anthropogenic, do not only influence Earth's climate, but also have adverse effects on human health, ecosystems, as well as on air quality. The global distribution of the aerosols is very uneven; therefore atmospheric particles have very different concentrations and composition depending on the region. In southern Europe, and in particular in the western Mediterranean region, the meteorological conditions with higher temperatures and lower precipitation, together with the abrupt topography around the Mediterranean Sea, hinder aerosol dispersion and prevent atmospheric wet-scavenging processes. Moreover, Mediterranean region is highly influenced by both anthropogenic emissions from shipping, power generation, industrial processes and road traffic, among others sources, and natural emissions from African dust outbreaks, soil resuspension, wildfires, sea spray, and vegetation. All these particular and complex atmospheric dynamics result in higher concentrations of aerosols around the Mediterranean Basin than in northern Europe. A detailed study of the physical, optical and chemical properties of the continental background aerosols measured at Montsec (MSC) monitoring station is presented in this work. The MSC mountain site (1570 m a.s.l.) was established during the development of this thesis; it is located in the western Mediterranean and became a member of the GAW (Global Atmosphere Watch) network in 2014. Aerosol properties (particle mass (PM), particle number (N), absorption, scattering and chemical composition) from MSC were found to be comparable in magnitude to those from other remote sites in Europe, when removing African dust outbreaks influence. This suggests that a continental background designation for MSC site is applicable. Nevertheless, some differences between MSC and other European remote sites highlight the importance of new particle formation (NPF) processes as a source of particles, the lower contribution of combustion and industrial processes, the greater impact of shipping emissions, and the higher influence of biogenic emissions. Moreover, these differences corroborate the important contribution of long-range transport of mineral dust and reveal a high impact of regional dust resuspension in the western Mediterranean region. Continental background aerosols in this region are affected by natural and anthropogenic emissions which results in a PM1 (PM of diameter less than 1 µm) comprised of (in decreasing concentrations) organic matter, sulfate, ammonium, mineral matter, nitrate, elemental carbon, sea salt and trace elements. The foremost PM1-10 (PM of diameter between 1 and 10 µm) constituent is mineral matter, followed by organic matter, nitrate, sulfate, sea salt, ammonium and elemental carbon. Comparison of absorption measurements with those of elemental carbon revealed an average mass absorption cross section (MAC) at MSC of 9.1 m-2/ g. A clear seasonal variation is observed for the majority of the aerosol parameters measured at MSC, with the highest values in summer and the lowest in winter, except for nitrate, in agreement with previous studies in the western Mediterranean. The reduced human activity at the weekend is reflected in the concentrations of PM1 and BC (black carbon) with a delay of one day (minimum on Sunday and Monday), which confirms that MSC is located at a sufficient distance from direct anthropogenic emissions, although it is still affected by them. The intra-day variation of PM, BC, scattering and PM1 major inorganic components (sulfate, nitrate, ammonium and chloride) shows poorly defined daily patterns in summer but clearer in winter, whereas concentrations of N and submicron organic aerosol show marked diurnal cycles throughout the year and regardless of the air mass origin, with a clear increase around midday.