Phase relations in the Cabeza de Araya cordierite monzogranite, Iberian Massif : implications for the formation of cordierite in a crystal mush
García-Moreno, Olga (Universidad de Oviedo. Departamento de Geología)
Corretgé Castañón, Luis Guillermo (Universidad de Oviedo. Departamento de Geología)
Holtz, F. (Leibniz Universität Hannover. Institut für Mineralogie)
García-Arias, M. (Universidad de Los Andes. Departmento de Geociencias)
Rodríguez, C. (Universidad de Huelva. Departamento de Ciencias de la Tierra)

Data:	2017
Resum:	Experimental investigations and thermodynamic calculations of the phase relations of a cordierite-rich monzogranite from the Cabeza de Araya batholith (Cáceres, Spain) have been performed to understand the formation of cordierite. The experiments failed to crystallize cordierite in the pressure range 200-600MPa, in the temperature range 700-975ºC and for different water activities (melt water contents between 2 and 6 wt. %). In contrast, clinopyroxene and orthopyroxene (absent in the natural mineral rock assemblage), together with biotite, were observed as ferromagnesian assemblage in a wide range of experimental conditions. Thermodynamic calculations, using the software PERPLE_X, describe the formation of cordierite only at 200 and 400MPa and very low water contents, and the amount of cordierite formed in the models is always below 3. 5 vol. %. The results indicate that cordierite is not in equilibrium with the bulk rock compositions. The most probable explanation was that cordierite nucleated and crystallized from a melt that is not in equilibrium with part of the mineral assemblage present in the magma. This "non-reactive" mineral assemblage was mainly composed of plagioclase. The silicate melts from which cordierite crystallized was more Al-rich and K-rich than the silicate melt composition in equilibrium with the bulk composition. One possible process for the high Al content of the silicate melt is related to assimilation and partial melting of Al-rich metasediments. An exo-perictetic reaction is assumed to account for both textural and geochemical observations. On the other hand, hybridization processes typical for calc-alkaline series can also explain the high proportions of "non-reactive" minerals observed in relatively high temperature magmas. This study clearly demonstrates that silicate melts in a crystal mush can depart significantly from the composition of melt that should be in equilibrium with the bulk solid assemblage.
Drets:	Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan aquestes es distribueixin sota la mateixa llicència que regula l'obra original i es reconegui l'autoria de l'obra original.
Llengua:	Anglès
Document:	Article ; recerca ; Versió publicada
Matèria:	Cordierite ; Monzogranites experimental petrology ; Peritectic ; Pseudosections
Publicat a:	Geologica acta, Vol. 15 Núm. 4 (December 2017) , p. 337-359, ISSN 1696-5728

Adreça alternativa: https://raco.cat/index.php/GeologicaActa/article/view/330803
Adreça alternativa: https://revistes.ub.edu/index.php/GEOACTA/article/view/GeologicaActa2017.15.4.6
DOI: 10.1344/GeologicaActa2017.15.4.6

24 p, 3.4 MB

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